Coordination of aminoborane, NH(2)BH(2), dictates selectivity and extent of H(2) release in metal-catalysed ammonia borane dehydrogenation.
نویسندگان
چکیده
In situ(11)B NMR monitoring, computational modeling, and external trapping studies show that selectivity and extent of H(2) release in metal-catalysed dehydrogenation of ammonia borane, NH(3)BH(3), are determined by coordination of reactive aminoborane, NH(2)BH(2), to the metal center.
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عنوان ژورنال:
- Chemical communications
دوره 48 شماره
صفحات -
تاریخ انتشار 2008